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Polymeric Tris[trimethyltin( IV )]hexacyanocobaltate( III ), a Compound Non‐Analogous to “Super Prussian Blue,” and Its Tris[tricyclopentadienyluranium( IV )] Homologue
Author(s) -
Yünlü Kenan,
Höck Nils,
Fischer R. Dieter
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198508791
Subject(s) - prussian blue , tris , octahedron , chemistry , trigonal crystal system , crystallography , polymer , stereochemistry , polymer chemistry , crystal structure , organic chemistry , electrochemistry , biochemistry , electrode
The coordination polymer 1 with a three‐dimensional network of Co atoms is formed as shown below. Distorted octahedral Co(CN) 6 structural units are present in 1 , which are linked through SnMe 3 bridges such that the partial structures …CoCN → SnMe 3 ← NCCo… are formed. The Sn atoms are coordinated trigonal‐bipyramidally. Since, surprisingly, two‐thirds of the chains are nonlinear, no super Prussian blue analogue can form; such an analogue should contain cubic Co 8 cages.