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Cl 2 CClCl ⊙⊕ , Cl 2 CClBr ⊙⊕ , and Br 2 CBrCl ⊙⊕ by Gas‐Phase Decarbonylation of CX 3 COY ⊙⊕
Author(s) -
Drewello Thomas,
Weiske Thomas,
Schwarz Helmut
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198508691
Subject(s) - decarbonylation , dication , chemistry , gas phase , carbon tetrachloride , medicinal chemistry , ion , organic chemistry , catalysis
The long‐sought radical cation of carbon tetrachloride has been generated by decarbonylation of Cl 3 CCOCl ⊙⊕ in the gas phase and characterized as the stable isomer Cl 2 CClCl ⊙⊕ . The theoretically predicted properties were experimentally confirmed. The dication CCl 4 2⊕is known.