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Electrochemical Methoxylation of Antipyrine
Author(s) -
Kaupp Gerd,
Köleli Fatih,
Gründken Eleonore
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198508641
Subject(s) - demethylation , regioselectivity , electrolysis , chemistry , electrochemistry , organic chemistry , biochemistry , catalysis , electrode , gene expression , electrolyte , dna methylation , gene
Regioselective attack on the N ‐methyl group takes place upon electrolysis of antipyrine in an undivided cell. The product 1 is of interest as, among other things, a model compound for the metabolism of antipyrine, which results in demethylation.