Reactions in the Ligand Sphere of Iron( II ): Synthesis of Crown Ethers | Zendy

Meier Kurt | Zendy; Rihs Grety | Zendy

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Reactions in the Ligand Sphere of Iron( II ): Synthesis of Crown Ethers

Author(s) -

Meier Kurt,

Rihs Grety

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198508581

Subject(s) - chemistry , crown ether , ligand (biochemistry) , lewis acids and bases , crown (dentistry) , ether , stereochemistry , polymer chemistry , crystallography , organic chemistry , catalysis , ion , materials science , receptor , biochemistry , composite material

The iron sandwich complex 2 containing two [12]crown‐4 ligands is formed upon irradiation of the arene‐iron complexes 1 in the presence of ethyleneoxide. The Lewis acid activity of the intermediate iron complex that is photochemically formed is decisive for this specific crown ether synthesis. The structure of 2 was determined by X‐ray diffraction.

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