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Do Cp(CO) 2 Mn Fragments Stabilize Radicals?
Author(s) -
Gross Renate,
Kaim Wolfgang
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198508561
Subject(s) - manganese , radical , chemistry , paramagnetism , electron paramagnetic resonance , nucleophile , ion , crystallography , spectroscopy , photochemistry , nuclear magnetic resonance , catalysis , organic chemistry , physics , condensed matter physics , quantum mechanics
Two classes of paramagnetic manganese complexes can be differentiated by ESR spectroscopy: radical complexes 1 , in which radical‐anion ligands L ⊙⊖ are stabilized by Cp(CO) 2 Mn 1 fragments, and low‐spin Mn 11 compounds 2 , with strongly nucleophilic ligands L.