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Diboriranides and a 1,3‐Diboraallyl System with B H B Bridge
Author(s) -
Wehrmann Rolf,
Meyer Harald,
Berndt Armin
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507881
Subject(s) - protonation , ring (chemistry) , potassium , chemistry , bridge (graph theory) , atom (system on chip) , stereochemistry , medicinal chemistry , crystallography , ion , organic chemistry , engineering , biology , anatomy , embedded system
The first three‐membered ring anions 1a, b containing two B atoms and one C atom have been isolated as the potassium salts. Surprisingly, Protonation leads to formation of isolable H‐bridged species 2 (RSiMe 3 , R′ t Bu).
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