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[L 2 Fe 2 II (μ‐OH)(μ‐CH 3 CO 2 ) 2 ](ClO 4 )·H 2 O, a Model Compound for the Diiron Centers in Deoxyhemerythrin
Author(s) -
Chaudhury Phalguni,
Wieghardt Karl,
Nuber Bernhard,
Weiss Johannes
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507781
Subject(s) - ligand (biochemistry) , chemistry , crystallography , center (category theory) , stereochemistry , biochemistry , receptor
The active center of deoxyhemerythrin and the title compound 1 have similar structures and similar magnetic and spectroscopic properties. In both cases, two Fe II centers are bridged by two carboxylato ligands and one hydroxo ligand.