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Total Synthesis of (±)‐Bonellin Dimethyl Ester
Author(s) -
Montforts FranzPeter,
Schwartz Ulrich M.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507751
Subject(s) - derivative (finance) , total synthesis , chemistry , malonic acid , porphyrin , organic chemistry , economics , financial economics
The sex‐differentiating pheromone of the marine animal Bonellia viridis , the porphyrin derivative bonellin, could be synthesized as the rac‐dimethyl ester 1 . The starting materials were four monocyclic building blocks and a selectively cleavable malonic ester (R 1 CH 3 ).