Decabenzylgermanocene: Synthesis and Structure of a Monomeric, Air‐Stable Germanocene | Zendy

Schumann Hebert | Zendy; Janiak Christoph | Zendy; Hahn Ekkehardt | Zendy; Loebel Jörg | Zendy; Zuckerman Jerold J. | Zendy

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Decabenzylgermanocene: Synthesis and Structure of a Monomeric, Air‐Stable Germanocene

Author(s) -

Schumann Hebert,

Janiak Christoph,

Hahn Ekkehardt,

Loebel Jörg,

Zuckerman Jerold J.

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198507731

Subject(s) - lone pair , germanium , ring (chemistry) , atom (system on chip) , monomer , cyclopentadienyl complex , crystallography , electron , chemistry , shield , materials science , atomic physics , physics , silicon , molecule , organic chemistry , nuclear physics , geology , engineering , catalysis , embedded system , polymer , petrology

Three of the benzyl groups in the germanocene 1 form a kind of protective shield for the lone pair electrons of the central germanium atom . This has been demonstrated by an X‐ray structure analysis. 1 is the first germanocene that, despite non‐parallel cyclopentadienyl ring planes, is air stable.

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