Reductive Carbonylation of  o ‐Nitrophenol with a Fe‐Pd Cluster‐Derived Heterogeneous Catalyst; CO Migration in [FePdPt(CO) 4 (Ph 2 PCH 2 PPh 2 ) 2 ] | Zendy

Braunstein Pierre | Zendy; Kervennal Jacques | Zendy; Richert JeanLuc | Zendy

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Reductive Carbonylation of o ‐Nitrophenol with a Fe‐Pd Cluster‐Derived Heterogeneous Catalyst; CO Migration in [FePdPt(CO) 4 (Ph 2 PCH 2 PPh 2 ) 2 ]

Author(s) -

Braunstein Pierre,

Kervennal Jacques,

Richert JeanLuc

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198507681

Subject(s) - carbonylation , catalysis , palladium , chemistry , selectivity , oxalate , nitrophenol , 4 nitrophenol , cluster (spacecraft) , inorganic chemistry , carbon monoxide , organic chemistry , computer science , programming language

High activity and selectivity is exhibited by the FePd cluster 1 on SiO 2 in the reductive carbonylation of o ‐nitrophenol to benzoxazol‐2‐one. A conventional catalyst prepared from iron oxalate and palladium acetate is far less effective. The catalyst prepared from 1 retains its activity even after repeated use.

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