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Reductive Carbonylation of o ‐Nitrophenol with a Fe‐Pd Cluster‐Derived Heterogeneous Catalyst; CO Migration in [FePdPt(CO) 4 (Ph 2 PCH 2 PPh 2 ) 2 ]
Author(s) -
Braunstein Pierre,
Kervennal Jacques,
Richert JeanLuc
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507681
Subject(s) - carbonylation , catalysis , palladium , chemistry , selectivity , oxalate , nitrophenol , 4 nitrophenol , cluster (spacecraft) , inorganic chemistry , carbon monoxide , organic chemistry , computer science , programming language
High activity and selectivity is exhibited by the FePd cluster 1 on SiO 2 in the reductive carbonylation of o ‐nitrophenol to benzoxazol‐2‐one. A conventional catalyst prepared from iron oxalate and palladium acetate is far less effective. The catalyst prepared from 1 retains its activity even after repeated use.