Premium
Novel High‐Nuclearity HgCoRu and HgCoFe Sandwich Complexes. Synthesis and Structure of [Hg{RuCo 3 (μ‐CO) 3 (CO) 9 } 2 ]
Author(s) -
Braunstein Pierre,
Rosé Jacky,
Tiripicchio Antonio,
Camellini Marisa Tiripicchio
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507671
Subject(s) - disproportionation , tetrahedron , crystallography , crystal structure , materials science , ion , chemistry , catalysis , organic chemistry , biochemistry
Two RuCo 3 tetrahedra, which are joined by a Hg 2+ ion , are present in the sandwich complex 1. The complex 1 is formed—along with HgBr 2 —in the disproportionation of BrHg[RuCo 3 (CO) 12 ]; crystals suitable for an X‐ray structure analysis are obtained directly.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom