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A New Type of Sandwich Complex Formed by Ag 1 and [Pt 3 (μ 2 ‐CO) 3 (P i Pr 3 ) 3 ]
Author(s) -
Albinati Alberto,
Dahmen KlausHermann,
Togni Antonio,
Venanzi Luigi M.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507661
Subject(s) - heteronuclear molecule , crystallography , type (biology) , ion , salt (chemistry) , physics , chemistry , stereochemistry , materials science , nuclear magnetic resonance spectroscopy , geology , quantum mechanics , paleontology
One of the lesser known heteronuclear Ag clusters is the sandwich complex cation 1 , in which two [Pt 3 (μ 2 ‐CO) 3 (P i Pr 3 ) 3 ] moieties are coupled by a Ag + ion. 1 could be isolated as the CF 3 SO 3 −salt in the form of air‐stable, dark‐red, prismatic crystals.