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How is Phosphorus Bound in 2‐Phospha‐ and 2‐“Phosphoniaallyl” Cations?
Author(s) -
Day Roberta O.,
Willhalm Angela,
Holmes Joan M.,
Holmes Robert R.,
Schmidpeter Alfred
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507641
Subject(s) - cationic polymerization , phosphorus , chemistry , methylation , ion , medicinal chemistry , inorganic chemistry , organic chemistry , biochemistry , dna
The conjugation in the 2‐phosphaallyl cation 1 is removed upon methylation to the doubly positively charged species 2, a phosphane with two cationic substituents.
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