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Dinuclear Nickel Complexes with Bridging Allyl Ligands
Author(s) -
Hanko Rudolf
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507041
Subject(s) - halogen , nickel , chemistry , alkyl , bridging (networking) , stereochemistry , polymer chemistry , medicinal chemistry , organic chemistry , computer network , computer science
The first synthesis of an allyl‐bridged Ni‐Ni complex such as 1 (R, R′ alkyl, X halogen, C 3 H 5 ) was achieved by reaction of Ni 0 and Ni 11 complexes in the presence of triorganophosphanes. Analogous Pd and Pt complexes have long been known.