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Cleavage of a CC Bond in the Catalytic Hydrosilylation of Camphor Oxime
Author(s) -
Brunner Henri,
Becker Richard
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507031
Subject(s) - hydrosilylation , oxime , camphor , chemistry , bond cleavage , catalysis , atom (system on chip) , medicinal chemistry , cleavage (geology) , stereochemistry , organic chemistry , materials science , fracture (geology) , computer science , composite material , embedded system
Surprisingly, metal‐catalyzed hydrosilylation of camphor oxime 1 does not lead to bornylamine but rather, enantioselectively, to 1‐(2‐aminoethyl)‐2,2,3‐trimethylcyclopentane 2 . The bond between the bridgehead C atom and the oxime C atom is cleaved in the reaction.