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Synthesis and Structure of the Spirocluster [(η 5 ‐C 5 H 5 ) 3 Mo 3 As(CO) 6 {CHP(C 6 H 5 ) 3 }]
Author(s) -
Blechschmitt Klaus,
Zahn Thomas,
Ziegler Manfred L.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198507021
Subject(s) - cluster (spacecraft) , transition metal , crystallography , group (periodic table) , element (criminal law) , physics , chemistry , materials science , atomic physics , computer science , catalysis , political science , law , biochemistry , quantum mechanics , programming language
An alkylidene group that bridges a maingroup element and a transition‐metal element is present in the spiro cluster 1 . Complex 1 was prepared from [(η 5 ‐C 5 H 5 ) 3 Mo 3 (CO) 6 (μ 3 ‐As)] and the Wittigreagent (C 6 H 5 ) 3 PCH 2 .