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Tridentate Oxygen Ligands as Cyclopentadienyl Equivalents: Structure and Properties of [LRh(μ‐CO) 3 RhL], L − = [(C 5 H 5 )Co{P( O )R 2 } 3 ] −
Author(s) -
Kläui Wolfgang,
Scotti Mario,
Valderrama Mauricio,
Rojas Soledad,
Sheldrick George M.,
Jones Peter G.,
Schroeder Tina
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198506831
Subject(s) - cyclopentadienyl complex , chemistry , oxygen , stereochemistry , medicinal chemistry , inert , oxygen atom , crystallography , molecule , catalysis , organic chemistry
The anionic half‐sandwich complexes L − (ROMe, OEt) act as tridentate ligands . They form inert complexes with metals in low oxidation states, an unusual behavior for oxygen ligands. For example, the Co 2 Rh 2 complex [LRh(μ‐CO) 3 RhL], ROEt, was prepared and its structure determined by X‐ray analysis.