Tridentate Oxygen Ligands as Cyclopentadienyl Equivalents: Structure and Properties of [LRh(μ‐CO) 3 RhL], L −  = [(C 5 H 5 )Co{P( O )R 2 } 3 ] − | Zendy

Kläui Wolfgang | Zendy; Scotti Mario | Zendy; Valderrama Mauricio | Zendy; Rojas Soledad | Zendy; Sheldrick George M. | Zendy; Jones Peter G. | Zendy; Schroeder Tina | Zendy

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Tridentate Oxygen Ligands as Cyclopentadienyl Equivalents: Structure and Properties of [LRh(μ‐CO) 3 RhL], L − = [(C 5 H 5 )Co{P( O )R 2 } 3 ] −

Author(s) -

Kläui Wolfgang,

Scotti Mario,

Valderrama Mauricio,

Rojas Soledad,

Sheldrick George M.,

Jones Peter G.,

Schroeder Tina

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198506831

Subject(s) - cyclopentadienyl complex , chemistry , oxygen , stereochemistry , medicinal chemistry , inert , oxygen atom , crystallography , molecule , catalysis , organic chemistry

The anionic half‐sandwich complexes L − (ROMe, OEt) act as tridentate ligands . They form inert complexes with metals in low oxidation states, an unusual behavior for oxygen ligands. For example, the Co 2 Rh 2 complex [LRh(μ‐CO) 3 RhL], ROEt, was prepared and its structure determined by X‐ray analysis.

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