Reaction of Homobenzvalene with Tetracyanoethylene; Formation of a Tetracyanodihydrobarbaralane Derivative and a Tetracyanocyclopropane Derivative | Zendy

Christl Manfred | Zendy; Lang Reinhard | Zendy; Herzog Clemens | Zendy; Stangl Roland | Zendy; Peters Karl | Zendy; Peters EvaMaria | Zendy; von Schnering Hans Georg | Zendy

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Reaction of Homobenzvalene with Tetracyanoethylene; Formation of a Tetracyanodihydrobarbaralane Derivative and a Tetracyanocyclopropane Derivative

Author(s) -

Christl Manfred,

Lang Reinhard,

Herzog Clemens,

Stangl Roland,

Peters Karl,

Peters EvaMaria,

von Schnering Hans Georg

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198506111

Subject(s) - tetracyanoethylene , derivative (finance) , cyclopropane , chemistry , photochemistry , organic chemistry , ring (chemistry) , financial economics , economics

Benzvalene and homobenzvalene 1 react differently with tetracyanoethylene (TCNE) . While benzvalene furnishes only a few percent of the 1,4‐cycloadduct, the analogous formation of 2 from 1 is the main reaction; the formation of the cyclopropane derivative 3 from 1 appears to be without example.

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