Premium
Reaction of Homobenzvalene with Tetracyanoethylene; Formation of a Tetracyanodihydrobarbaralane Derivative and a Tetracyanocyclopropane Derivative
Author(s) -
Christl Manfred,
Lang Reinhard,
Herzog Clemens,
Stangl Roland,
Peters Karl,
Peters EvaMaria,
von Schnering Hans Georg
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198506111
Subject(s) - tetracyanoethylene , derivative (finance) , cyclopropane , chemistry , photochemistry , organic chemistry , ring (chemistry) , financial economics , economics
Benzvalene and homobenzvalene 1 react differently with tetracyanoethylene (TCNE) . While benzvalene furnishes only a few percent of the 1,4‐cycloadduct, the analogous formation of 2 from 1 is the main reaction; the formation of the cyclopropane derivative 3 from 1 appears to be without example.