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Bis(dihydro‐1,2‐azaborolyl)tin—a Novel Boron‐Nitrogen Stannocene
Author(s) -
Schmid Günter,
Zaika Dagmar,
Boese Roland
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198506021
Subject(s) - boron , tin , diastereomer , nitrogen , orange (colour) , chemistry , spectroscopy , crystallography , materials science , stereochemistry , organic chemistry , physics , food science , quantum mechanics
The sandwich complex 1 , which decomposes above −20°C, contains two dihydro‐1,2‐azaborolyl ligands at an angle of 46.5°. Two diastereomers of 1 can be detected by 1 HNMR spectroscopy. 1 forms orange‐yellow crystals.
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