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3,8‐Methanoaza[10]annulene (Homoisoquinoline)
Author(s) -
Tückmantel Werner,
Andree Gertraud,
Seidel Andreas,
Schmickler Hans,
Lex Johann,
Kraka Elfi,
Haug Michael,
Cremer Dieter,
Vogel Emanuel
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505921
Subject(s) - annulene , derivative (finance) , chemistry , medicinal chemistry , stereochemistry , computational chemistry , business , finance
The second aza‐analogue of 1,6‐methano[10]annulene , the “homoisoquinoline” 2 , has been synthesized in a multistep reaction via 3 . Unlike 1, 2 rapidly polymerizes, even in absence of air. According to its spectra and an X‐ray structure analysis (of a derivative) 2 is an aromatic compound.