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Stepwise Formation of a Dinuclear μ‐Aminocarbyne‐ and a μ‐Formimidoyl‐Metal Complex by Insertion of Methyl Isocyanide into an MHM Bridge
Author(s) -
Zolk Ralf,
Werner Helmut
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505771
Subject(s) - chemistry , methylamine , isocyanide , ligand (biochemistry) , bridge (graph theory) , metal , medicinal chemistry , stereochemistry , polymer chemistry , organic chemistry , biochemistry , medicine , receptor
Addition of the donor ligand MeNC to the dicobalt complex 1 proceeds with opening of the hydrido bridge. The aminocarbyne complex 2 that is formed rearranges in the presence of methylamine into the μ‐ N ‐methylformidoyl complex 3 (anion: PF 6 − ).
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