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An Organoboron Model System for the Fischer‐Tropsch Synthesis
Author(s) -
Köster Roland,
Yalpani Mohamed
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505721
Subject(s) - nonane , alkyl , organoboron compounds , chemistry , fischer–tropsch process , polymerization , model system , organic chemistry , medicinal chemistry , catalysis , computational chemistry , polymer , selectivity
The reductive C 1 ‐polymerization of metal‐coordinated CO , e.g. in Fe(CO) 5 , has been achieved with 9‐borabicyclo[3.3.1]nonane (9‐H‐9‐BBN). The compounds 9‐alkyl‐9‐BBN 1 are formed which mainly contain straight chain (but also methyl branched) alkyl residues.