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Bis(tricarbonyliron)‐ para ‐quinodimethanes: Preparation and Molecular Structure
Author(s) -
Koray Ali R.,
Krieger Claus,
Staab Heinz A.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505211
Subject(s) - trimethylenemethane , ring (chemistry) , ligand (biochemistry) , chemistry , stereochemistry , crystallography , organic chemistry , catalysis , receptor , biochemistry , cycloaddition
The stabilization of p ‐quinodimethanes can be achieved by complexation. According to an X‐ray structure analysis the two Fe(CO) 3 units in 1 , RCH 3 , are located on different sides of the slightly puckered six membered ring. The ligand in 1 formally contains two trimethylenemethane moieties.
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