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Reaction of Small Molecules with the Binuclear Complex [(μ‐C 5 H 5 )(μBr)Pd 2 (PR 3 ) 2 ]: Addition without Cleavage of the Metal‐Metal Bond
Author(s) -
Thometzek Peter,
Zenkert Karin,
Werner Helmut
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505161
Subject(s) - chemistry , palladium , molecule , bridge (graph theory) , cleavage (geology) , stereochemistry , crystallography , materials science , catalysis , organic chemistry , medicine , fracture (geology) , composite material
The Pd–Pd bond in the symmetrical complex 1 is very stable. It adds small ligands such as CO, CH 3 NC, and SO 2 (→ 2 ) in the bridge position; the bridge ligands Cp and Br thereby become terminal ligands.