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Pentacarbonylolefin‐ and Pentacarbonyldiolefinrhenium Complex Cations; Synthesis and Structure of the 2‐Butene‐1,4‐diyl‐Bridged Carbonyldirhenium Complex trans ‐[(OC) 5 ReCH 2 CHCHCH 2 Re(CO) 5 ]
Author(s) -
Beck Wolfgang,
Raab Klaus,
Nagel Ulrich,
Sacher Wolfgang
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198505051
Subject(s) - chemistry , crystallography , bridge (graph theory) , olefin fiber , stereochemistry , organic chemistry , medicine , polymer
Addition of the pentacarbonylrhenate ion to the coordinated olefin in the complex cation 1 leads to formation of the complex 2 , in which a σ‐η 1 ,σ‐η 1 ‐type C 4 H 6 ‐bridge is realized for the first time. The structure of 2 has been elucidated by an X‐ray structure analysis.