Premium
Nitrogen Monoxide as a Source for Oxo Ligands—Acetylene‐Oxo Complexes of Tungsten
Author(s) -
Alt Helmut G.,
Hayen Heidi I.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504971
Subject(s) - acetylene , carbon monoxide , alkyne , chemistry , nitrogen , fragmentation (computing) , ketone , tungsten , monoxide , ligand (biochemistry) , photochemistry , oxygen , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , operating system , biochemistry , receptor , computer science
The fragmentation of an alkenyl ketone ligand into an alkyne‐and methyl‐or acetylligand is surprisingly achieved in the reaction of CpW(CO) 2 CHCHCOCH 3 with nitrogen monoxide. NO provides its oxygen for the formation of an oxoligand.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom