Synthesis and Structure of New Potassium‐Gold‐Tellurium Polyanions: [KAu 9 Te 7 ] 4⊖ , [K 2 Au 4 Te 4 (en) 4 ] 2⊖ , and [K 2 Au 4 Te 4 (dmf) 2 (CH 3 OH) 2 ] 2⊖ | Zendy

Haushalter Robert C. | Zendy

Premium

Synthesis and Structure of New Potassium‐Gold‐Tellurium Polyanions: [KAu 9 Te 7 ] 4⊖ , [K 2 Au 4 Te 4 (en) 4 ] 2⊖ , and [K 2 Au 4 Te 4 (dmf) 2 (CH 3 OH) 2 ] 2⊖

Author(s) -

Haushalter Robert C.

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198504321

Subject(s) - tellurium , ion , crystallography , potassium , analytical chemistry (journal) , planar , chemistry , cube (algebra) , materials science , inorganic chemistry , metallurgy , mathematics , organic chemistry , chromatography , computer graphics (images) , combinatorics , computer science

By extraction of tertiary KAuTe alloys, the salts 1 – 3, which contain new KAuTe polyanions, could be obtained. The anion of 1 can be roughly described as a derivative of an [M 12 X 8 ] 4⊖ cube; in 2 and 3, planar [Au 4 Te 4 ] 4⊖ rings are present, the sides of which are capped by K ⊕ .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research