Synthesis of a Novel Stable Carbanion: 1,1,2‐Tricyano‐2‐(3,4‐dicyano‐5‐imino‐2,5‐dihydro‐1 H ‐pyrrol‐2‐ylidene)ethanide by Reduction of Tetracyanoethylene with Tris(2,2′‐bipyridine)titanium | Zendy

Dessy Giulia | Zendy; Fares Vincenzo | Zendy; Flamini Alberto | Zendy; Giuliani Anna Maria | Zendy

Premium

Synthesis of a Novel Stable Carbanion: 1,1,2‐Tricyano‐2‐(3,4‐dicyano‐5‐imino‐2,5‐dihydro‐1 H ‐pyrrol‐2‐ylidene)ethanide by Reduction of Tetracyanoethylene with Tris(2,2′‐bipyridine)titanium

Author(s) -

Dessy Giulia,

Fares Vincenzo,

Flamini Alberto,

Giuliani Anna Maria

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198504261

Subject(s) - tetracyanoethylene , chemistry , carbanion , medicinal chemistry , derivative (finance) , 2,2' bipyridine , salt (chemistry) , molecule , nitrile , tris , titanium , stereochemistry , crystal structure , crystallography , organic chemistry , biochemistry , financial economics , economics

The mechanism of reduction of tetracyanoethylene (TCNE) to the anionic dihydropyrrole derivative 1 with tris(2,2′‐bipyridine)titanium has been elucidated. 1 is formed via condensation of two TCNE molecules. The X‐ray structure analysis was carried out on a Ph 4 As salt of 1 . ◯ = N, • = C.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research