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Synthesis, Structure, and Reactivity of η 3 ‐1‐Azaallylmolybdenum Complexes
Author(s) -
Green Michael,
Mercer Richard J.,
Morton Carolyn E.,
Orpen A. Guy
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504221
Subject(s) - reactivity (psychology) , alkylation , hydrogen , chemistry , nitrogen , stereochemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology
Azirines and [Mo 2 (CO) 4 (η‐C 5 H 5 ) 2 ] are the starting materials for the title compounds 1 . These compounds can be alkylated on nitrogen, and a novel 1,3 hydrogen shift provides a route to azavinylidene complexes.
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