Premium
The First Arsirane
Author(s) -
Appel Rolf,
Gaitzsch Thomas,
Knoch Falk
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504191
Subject(s) - instability , lithium (medication) , materials science , physics , mineralogy , chemistry , psychology , mechanics , psychiatry
The instability of the arsorane 3, X = As, R = Ph, was exploited to prepare the first arsacyclopropane 4 . The colorless crystals of 4 form from 3 within 12 h at room temperature. 3 was obtained from the arsane 1 and the lithium methanide 2 .