Premium
Cyanogen as a Bridging Ligand—Preparation and Crystal Structure of Polymeric [Ag{(CN) 2 } 2 ] n [AsF 6 ] n with an Undulating Square Cationic Network
Author(s) -
Roesky Herbert W.,
Hofmann Hartmut,
Schimkowiak Jürgen,
Jones Peter G.,
MeyerBäse Karen,
Sheldrick George M.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504171
Subject(s) - cyanogen , crystallography , planar , nitrogen atom , crystal structure , metal , ligand (biochemistry) , atom (system on chip) , materials science , bridging (networking) , chemistry , organic chemistry , computer science , computer network , computer graphics (images) , embedded system , group (periodic table) , biochemistry , receptor
Of interest for metal‐catalyzed reactions of cyanogen is the structure of complexes containing this pseudohalogen. In the cation 1, the title compound is present in a polymeric network in which each silver atom is surrounded by a square‐planar array of nitrogen atoms.