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( Z )‐3,7‐Bis(phenylsulfonyl)pentacyclo[5.1.0.0 2,4 .0 3,5 .0 6,8 ]octane, an Octabisvalene Derivative
Author(s) -
Rücker Christoph,
Prinzbach Horst
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198504111
Subject(s) - valence (chemistry) , derivative (finance) , octane , chemistry , medicinal chemistry , organic chemistry , economics , financial economics
Octabisvalene, (CH) 8 , which still unknown, is the third saturated and highly strained valence isomer of cyclooctatetrane. The first crystalline derivative 1 , X = SO 2 C 6 H 5 , has been synthesized from cis ‐benzenetrioxide. 1 is stable up to ca. 200°C.
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