Complexes of 1,5‐Di( p ‐tolyl)‐1,4‐pentaazadien‐3‐ide, Crystal Structures of [Cu(tolylNNNNNtolyl)] 3  and [Ni(tolylNNNNNtolyl) 2 ] 2 | Zendy

Beck Johannes | Zendy; Strähle Joachim | Zendy

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Complexes of 1,5‐Di( p ‐tolyl)‐1,4‐pentaazadien‐3‐ide, Crystal Structures of [Cu(tolylNNNNNtolyl)] 3 and [Ni(tolylNNNNNtolyl) 2 ] 2

Author(s) -

Beck Johannes,

Strähle Joachim

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198504091

Subject(s) - crystallography , copper , ion , planar , paramagnetism , crystal (programming language) , metal , trigonal crystal system , chemistry , chain (unit) , crystal structure , materials science , physics , condensed matter physics , computer graphics (images) , organic chemistry , astronomy , computer science , programming language

Three linearly arranged Cu ⊕ ions, coordinated by three parallel N 5 zig‐zag chains in such a way that each metal ion is surrounded by a trigonal planar array of N atoms, are present in the pentaazadienide complex 1 . The red crystals of 1 exhibit weak paramagnetism; the CuCu distances in the chains are the shortest observed so far in copper( I ) complexes.

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