Reactivity of the [Fe 2 (μ 2 ‐O)(μ‐acetato) 2 ] Unit in Methemerythrin Model Compounds towards N       3    ⊖     and NCS ⊖ | Zendy

Wieghardt Karl | Zendy; Pohl Klaus | Zendy; Ventur D. | Zendy

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Reactivity of the [Fe 2 (μ 2 ‐O)(μ‐acetato) 2 ] Unit in Methemerythrin Model Compounds towards N 3 ⊖ and NCS ⊖

Author(s) -

Wieghardt Karl,

Pohl Klaus,

Ventur D.

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198503921

Subject(s) - reactivity (psychology) , chemistry , carboxylate , medicinal chemistry , stereochemistry , crystallography , medicine , alternative medicine , pathology

The enzyme deoxyhemerythrin reacts in a completely different manner with N 3 ⊖and NCS ⊖ than the methemerythrin model compounds containing the partial structure 1, L = N,N ′, N ″‐trimethyl‐1,4,7‐triazacyclononane. The [Fe 2 (μ 2 ‐O)(μ‐carboxylato) 2 ] group of the enzyme remains intact, whereas in the model compound the carboxylato bridges and the oxo bridges are replaced.

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