Hexaphosphabenzene as Complex Ligand | Zendy

Scherer Otto J. | Zendy; Sitzmann Helmut | Zendy; Wolmershäuser Gotthelf | Zendy

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Hexaphosphabenzene as Complex Ligand

Author(s) -

Scherer Otto J.,

Sitzmann Helmut,

Wolmershäuser Gotthelf

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198503511

Subject(s) - ligand (biochemistry) , ring (chemistry) , colored , planar , crystallography , chemistry , aromaticity , stereochemistry , materials science , molecule , computer science , organic chemistry , computer graphics (images) , composite material , biochemistry , receptor

Hexaphosphabenzene, P 6 , long a goal of chemical synthesis, has been obtained for the first time as a complex‐stabilized ligand. The triple‐decker sandwich complex 1 forms air‐stable, amber‐colored crystals. According to an X‐ray structure analysis, the aromatic P 6 ring is planar and lies parallel to the two five‐membered rings.

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