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A New, Facile Route to 2‐Azaallenium Salts—Bis(2‐adamantylidene)ammonium Hexachloroantimonate
Author(s) -
Würthwein ErnstUlrich,
Kupfer Rainer,
Budzelaar Peter H. M.,
Strobel Cornelia,
Beck Horst P.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198503401
Subject(s) - alicyclic compound , salt (chemistry) , isocyanate , ammonium , chemistry , double salt , polymer chemistry , organic chemistry , polyurethane
A double isocyanate reaction affords the title compound 1, the first pure, alicyclic, substituted 2‐aza‐allenium salt. An X‐ray structure determination was carried out on 1 . 2‐Aza‐allenium salts have been proposed as intermediates in S N l reactions.