Activation Energy of the Racemization of Optically Active Tricarbonyl(tropone)iron Complexes | Zendy

Tajiri Akio | Zendy; Morita Noboru | Zendy; Asao Toyonobu | Zendy; Hatano Masahiro | Zendy

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Activation Energy of the Racemization of Optically Active Tricarbonyl(tropone)iron Complexes

Author(s) -

Tajiri Akio,

Morita Noboru,

Asao Toyonobu,

Hatano Masahiro

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198503291

Subject(s) - racemization , tropone , circular dichroism , enantiomer , activation energy , chemistry , resolution (logic) , intermolecular force , photochemistry , optically active , crystallography , stereochemistry , organic chemistry , molecule , artificial intelligence , computer science

Following HPLC resolution of the enantiomers of 1 and 2, the activation energy for the racemization of 1 was determined to be 25.8 kcal/mol by circular dichroism measurements. 2 does not racemize under the same conditions, since, in this case, an intermolecular process would be required.

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