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CC Bond Formation of Alkenes with Isocyanates on Ni 0 Complexes—a New Synthesis of Acrylamides
Author(s) -
Hoberg Heinz,
Sümmermann Klaus,
Milchereit Armin
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198503252
Subject(s) - chemistry , bond , medicinal chemistry , polymer chemistry , business , finance
The first metal‐induced synthesis of an acrylic acid derivative 4 from a non‐activated alkene 1 and an isocyanate 2 takes place via CC coupling to give an azanickelacyclopentanone 3. 4 is immediately formed upon heating 3 .