Bis[( R )‐(+)‐binap]rhodium( I ) Perchlorate, a Highly Efficient Catalyst for the Asymmetric Isomerization of Allylamines | Zendy

Tani Kazuhide | Zendy; Yamagata Tsuneaki | Zendy; Tatsuno Yoshitaka | Zendy; Yamagata Yuriko | Zendy; Tomita Kenichi | Zendy; Akutagawa Susumu | Zendy; Kumobayashi Hidenori | Zendy; Otsuka Sei | Zendy

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Bis[( R )‐(+)‐binap]rhodium( I ) Perchlorate, a Highly Efficient Catalyst for the Asymmetric Isomerization of Allylamines

Author(s) -

Tani Kazuhide,

Yamagata Tsuneaki,

Tatsuno Yoshitaka,

Yamagata Yuriko,

Tomita Kenichi,

Akutagawa Susumu,

Kumobayashi Hidenori,

Otsuka Sei

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198502171

Subject(s) - binap , isomerization , rhodium , chemistry , dissociation (chemistry) , catalysis , medicinal chemistry , photochemistry , organic chemistry , enantioselective synthesis

The dissociation of an R ‐binap ligand accounts for the high catalytic activity of 1 in the asymmetric isomerization of allylamines. An X‐ray structure analysis of 1 , prepared in the form of deep red crystals from [Rh( R ‐binap)(cod)] ⊕ ClO 4 ⊖by exchange of cyclooctadiene (cod) for R ‐binap, was carried out (binap = P,P ′‐(1,1′‐binaphthyl‐2,2′‐diyl)bis(diphenylphosphane)).

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