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Pentamethyldiethylenetriamine(phenyl)lithium, a Monomeric Organolithium Compound
Author(s) -
Schümann Uwe,
Kopf Jürgen,
Weiss Erwin
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198502151
Subject(s) - phenyllithium , tetramer , dimer , chemistry , monomer , lithium (medication) , ligand (biochemistry) , ether , solvation , stereochemistry , organic chemistry , molecule , polymer , biochemistry , psychology , receptor , enzyme , psychiatry
The degree of association of phenyllithium is decisively influenced by solvation. Thus far it has only been known as a dimer and tetramer with ether and tetramethylethylene‐diamine as ligands. The stabilization of monomeric phenyllithium with the tridentate ligand pentamethyldiethylenetriamine has now been achieved.