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Cofacial Dimer of a Diiminosuccinonitrile Complex Containing a Co II Co II Bond and its Reduction to Monomeric Co I Complex
Author(s) -
Peng ShieMing,
Liaw DerShin,
Wang Yu,
Simon Arndt
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198502101
Subject(s) - chemistry , monomer , dimer , stereochemistry , crystallography , polymer chemistry , polymer , organic chemistry
The blue binuclear complex 1 , which can be obtained from diaminomaleonitrile with Co(OAc) 2 followed by oxidation with O 2 , exhibits a strong CoCo σ‐bond and a δ‐bond between the two parallel semidiimino‐succinonitrile ligands. A localization of the double bonds in the ligands results from this bonding situation.