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Synthesis of [Et 2 NCW(CO) 2 (μ‐PPh 2 ) 2 Mo(CO) 4 ] ⊖ , the First Anionic Carbynemetal Complex; Addition of CO 2 to the WC Bond
Author(s) -
Fischer Ernst Otto,
Filippou Alexander C.,
Alt Helmut G.,
Thewalt Ulf
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198502031
Subject(s) - ion , chemistry , crystallography , organic chemistry
A spirocyclic heterobinuclear complex , the oxatungstacyclobutenone 2 , is formed in the reaction of CO 2 with 1 , the first carbynemetal complex anion. In addition to this reaction, spectroscopic results support the structure of 1 .