Synthesis of [(C 5 Me 5 ) 2 Mo 2 XS 3 Co(CO) 2 ] Clusters (X = P, As) and Structural Characterization of a μ 2 , η 2 ‐AsS Ligand | Zendy

Brunner Henri | Zendy; Kauermann Heike | Zendy; Klement Ulrich | Zendy; Wachter Joachim | Zendy; Zahn Thomas | Zendy; Ziegler Manfred L. | Zendy

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Synthesis of [(C 5 Me 5 ) 2 Mo 2 XS 3 Co(CO) 2 ] Clusters (X = P, As) and Structural Characterization of a μ 2 , η 2 ‐AsS Ligand

Author(s) -

Brunner Henri,

Kauermann Heike,

Klement Ulrich,

Wachter Joachim,

Zahn Thomas,

Ziegler Manfred L.

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198501321

Subject(s) - cluster (spacecraft) , bond length , crystallography , order (exchange) , ligand (biochemistry) , materials science , physics , chemistry , crystal structure , computer science , biochemistry , receptor , programming language , finance , economics

The first complex with AsS as ligand , the trinuclear cluster 1 , was obtained from the dinuclear complex [(C 5 Me 5 ) 2 Mo 2 As 2 S 3 ] and Co 2 (CO) 8 and characterized by X‐ray structure analysis. It is concluded from the bond lengths that AsS has a bond order of 1 and functions as a 5e‐donor.—The cluster 2 was prepared analogously.

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