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Synthesis and structure of [Pt 2 (μ‐H)(μ‐CHCH 2 Ph)(diphos) 2 ][BF 4 ]
Author(s) -
Minghetti Giovanni,
Albinati Alberto,
Bandini Anna Laura,
Banditelli Guido
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198501201
Subject(s) - hydride , crystallography , ligand (biochemistry) , bridge (graph theory) , chemistry , metal , styrene , organic chemistry , copolymer , medicine , biochemistry , receptor , polymer
The first compound in which a hydride‐ and an alkylidene‐ligand bridge two Pt‐atoms is present in the complex cation 2 , which is formed on reaction of the complex 1 with styrene. 2 was characterized NMR spectroscopically and by an X‐ray structure analysis. the PtPt distance of 2.735(1) Å indicates that there is bonding interaction between the two metal atoms.