Synthesis and structure of [Pt 2 (μ‐H)(μ‐CHCH 2 Ph)(diphos) 2 ][BF 4 ] | Zendy

Minghetti Giovanni | Zendy; Albinati Alberto | Zendy; Bandini Anna Laura | Zendy; Banditelli Guido | Zendy

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Synthesis and structure of [Pt 2 (μ‐H)(μ‐CHCH 2 Ph)(diphos) 2 ][BF 4 ]

Author(s) -

Minghetti Giovanni,

Albinati Alberto,

Bandini Anna Laura,

Banditelli Guido

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198501201

Subject(s) - hydride , crystallography , ligand (biochemistry) , bridge (graph theory) , chemistry , metal , styrene , organic chemistry , copolymer , medicine , biochemistry , receptor , polymer

The first compound in which a hydride‐ and an alkylidene‐ligand bridge two Pt‐atoms is present in the complex cation 2 , which is formed on reaction of the complex 1 with styrene. 2 was characterized NMR spectroscopically and by an X‐ray structure analysis. the PtPt distance of 2.735(1) Å indicates that there is bonding interaction between the two metal atoms.

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