[Mn(S 2 C 6 H 3 Me)2] n− : Mononuclear Manganese Complexes with Square‐Planar (n = 1) and Distorted Tetrahedral (n = 2) Sulfur Coordination | Zendy

Henkel Gerald | Zendy; Greiwe Klaus | Zendy; Krebs Bernt | Zendy

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[Mn(S 2 C 6 H 3 Me)2] n− : Mononuclear Manganese Complexes with Square‐Planar (n = 1) and Distorted Tetrahedral (n = 2) Sulfur Coordination

Author(s) -

Henkel Gerald,

Greiwe Klaus,

Krebs Bernt

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198501171

Subject(s) - manganese , chemistry , sulfur , square pyramidal molecular geometry , crystallography , tetrahedron , inorganic chemistry , crystal structure , organic chemistry

The unusual planar manganese( III )‐sulfur complex [Mn(S 2 C 6 H 3 Me)2] − 1 is formed on reaction of MnCl 2 ·4H 2 O with toluene‐3,4‐dithiolate in methanol in the presence of atmospheric oxygen. A further product is the square‐pyramidal complex containing an additional apical MeOH group. Reaction under anaerobic conditions leads to formation of the manganese( II )‐sulfur complex [Mn(S 2 C 6 H 3 Me) 2 ] 2− , which differs from 1 through its strongly distorted tetrahedral coordination.

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