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Amino(imino)phosphanes as Face‐Bridging Complex Ligands
Author(s) -
Scherer Otto J.,
Walter Richard,
Sheldrick William S.
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198501151
Subject(s) - bridging (networking) , chemistry , isocyanide , bridging ligand , ligand (biochemistry) , stereochemistry , cluster (spacecraft) , combinatorial chemistry , crystallography , crystal structure , biochemistry , receptor , computer science , computer network , programming language
A similar coordination behavior as isocyanide ligands is exhibited by R 2 NPNR ligands, since bridging isocyanide ligands are replaced by trivalent phosphazenes in the synthesis of the cluster 2 from the cluster 1 . 2 represents the first cluster in which an amino(imino)phosphane is found to function as face‐bridging ligand; a μ 3 ‐η 2 ‐CNCMe 3 ligand is also present.