Amino(imino)phosphanes as Face‐Bridging Complex Ligands | Zendy

Scherer Otto J. | Zendy; Walter Richard | Zendy; Sheldrick William S. | Zendy

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Amino(imino)phosphanes as Face‐Bridging Complex Ligands

Author(s) -

Scherer Otto J.,

Walter Richard,

Sheldrick William S.

Publication year - 1985

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198501151

Subject(s) - bridging (networking) , chemistry , isocyanide , bridging ligand , ligand (biochemistry) , stereochemistry , cluster (spacecraft) , combinatorial chemistry , crystallography , crystal structure , biochemistry , receptor , computer science , computer network , programming language

A similar coordination behavior as isocyanide ligands is exhibited by R 2 NPNR ligands, since bridging isocyanide ligands are replaced by trivalent phosphazenes in the synthesis of the cluster 2 from the cluster 1 . 2 represents the first cluster in which an amino(imino)phosphane is found to function as face‐bridging ligand; a μ 3 ‐η 2 ‐CNCMe 3 ligand is also present.

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