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Phenyl Silaisocyanide: The First Organosilicon Compound with a Formal SiN Triple Bond
Author(s) -
Bock Hans,
Dammel Ralph
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198501111
Subject(s) - organosilicon , x ray photoelectron spectroscopy , triple bond , silicon , chemistry , terminal (telecommunication) , stereochemistry , crystallography , polymer chemistry , double bond , organic chemistry , chemical engineering , computer science , engineering , telecommunications
The presumably linear CNSi group is present in phenyl silaisocyanide 3 , an organosilicon compound with terminal silicon of coordination number 1. 3 was generated pyrolytically from the triazidosilane 2 and characterized by photoelectron spectroscopy.