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(C 6 H 5 Sb) 6 ·(1,4‐dioxane), the First Cyclohexastibane
Author(s) -
Breunig Hans Joachim,
Häberle Karl,
Dräger Martin,
Severengiz Tevfik
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198500721
Subject(s) - antimony , 1,4 dioxane , ring (chemistry) , chemistry , polymer , polymer chemistry , crystallography , organic chemistry
A ring of six antimony atoms is contained in the title compound; it is the first of its type. Earlier attempts to synthesize it usually led to formation of solid polymers. 1 is formed when PhSb(SiMe 3 ) 2 in 1,4‐dioxane is oxidized by air. According to the X‐ray structure analysis no specific interactions occur between dioxane and Sb.