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Synthesis and Structure of a Thallium Complex with an Anionic Sandwich Complex Ligand
Author(s) -
Stumpf Klaus,
Pritzkow Hans,
Siebert Walter
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198500711
Subject(s) - thallium , ligand (biochemistry) , chemistry , molecule , cluster (spacecraft) , atom (system on chip) , crystallography , inorganic chemistry , organic chemistry , receptor , biochemistry , computer science , embedded system , programming language
The first sandwich complex with an apical thallium atom , 1 , is made up of the layers C 5 H 5 /Co/Me 4 (B 2 C 3 )H 2 /Tl. In contrast to polymeric Tl(C 5 H 5 ), 1 is a discrete molecule described as a closo ‐cluster.
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