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c‐TiS 2 , a New Modification of Titanium Disulfide with Cubic Structure
Author(s) -
Schöllhorn Robert,
Payer Andreas
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198500671
Subject(s) - metastability , materials science , hexagonal crystal system , electrolyte , lattice (music) , crystallography , titanium , electrode , disulfide bond , solid state , copper , chemical engineering , crystal structure , chemistry , metallurgy , organic chemistry , biochemistry , physics , acoustics , engineering
A metastable modification of TiS 2 has been prepared by a topotactic solid‐state reaction at room temperature in which CuTi 2 S 4 working electrodes were anodically oxidized in aprotic copper( I ) electrolytes. On the basis of X‐ray powder data, it can be determined that the new phase belongs to a very seldom AB 2 structural type. This cubic TiS 2 is of interest, inter alia, as a material for reversible electrodes in secondary batteries. It has advantages over hexagonal TiS 2 (layer lattice).
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